ISSN 2310-5283 e-ISSN 3041-1432 UDC 67; 68; 33
en

https://doi.org/10.62763/cb/2.2024.63

Vol. 17, No. 2, 2024

63-71

  • Read article

    • Abrasion resistance of titanium-based biofunctionalised oxide ceramic coatings

    Nataliia Imbirovych Maksym Boiarskyi Inna Boiarska

    Received 14.08.2024, Revised 10.11.2024, Accepted 03.12.2024

    Abstract

    The requirements of modern production for details are very high. Particular attention is paid to the friction resistance parts that work in the friction mechanism. Titanium alloys are characterised by low wear resistance and have the ability to stick to the surface of the body of greater hardness. Therefore, applying wearresistant coatings to the surface of titanium alloys is relevant. The purpose of this work was to increase the operational properties of titanium alloys by creating protective coatings on their surface. The work investigated the wear resistance of plasma electrolyte oxidised coatings on titanium alloy. Experimental studies revealed that the coatings have different oxides (stoichiometric and non-stoichiometric) in their structure. Nonstoichiometric oxides are characterised by low physical and mechanical properties and settle in the pores after primary wear. In the process of wear, a non-stoichiometric oxide serves as a lubricant. This has a positive effect on their tribological properties. It has been established that applying a coating to the surface of a titanium alloy increases the abrasion resistance by 10 times. The interface between the metal base and the coating is uneven, which is achieved due to the melting of the surface of the titanium alloy during PEO. This feature demonstrates the high adhesion properties of coatings formed by the PEO method to the titanium base. The paper established the dependence of the size and shape of the pores on the working modes. It was found that the size of the pores on the surface of the coating is 10...70 µm, and high internal porosity of the coating material was established. It was found that porous coatings melt internally, so the porosity is open, not through. The studied property of the coatings can help in implantology, since the connection of muscle tissue with the implant occurs without the formation of a capsule

    Keywords:

    phosphates; friction; plasma electrolytic oxidation; durability; wear; porosity

    Suggested citation
    Imbirovych, N., Boiarskyi, M., & Boiarska, I. (2024). Abrasion resistance of titanium-based biofunctionalised oxide ceramic coatings. Commodity Bulletin, 17(2), 63-71. https://doi.org/10.62763/cb/2.2024.63
    561 Views

    References

    [1] Aliasghari, S., Skeldon, P., & Thompson, G.E. (2014). Plasma electrolytic oxidation of titanium in a phosphate/silicate electrolyte and tribological performance of the coatings. Applied Surface Science, 316, 463-476. doi: 10.1016/j.apsusc.2014.08.037.

    [2] Babaei, K., Fattah-alhosseini, A., & Molaei, M. (2020). The effects of carbon-based additives on corrosion and wear properties of plasma electrolytic oxidation (PEO) coatings applied on aluminum and its alloys: A review. Surfaces and Interfaces, 21, article number 100677. doi: 10.1016/j.surfin.2020.100677.

    [3] Bocchetta P., Chen L.-Y., Tardelli J.D.C., dos Reis, A.C., Almeraya-Calderón, F., & Leo, P. (2021). Passive layers and corrosion resistance of biomedical Ti-6Al-4V and β-Ti alloys. Coatings, 11(5), article number 487. doi: 10.3390/coatings11050487.

    [4] Elias, L.M., Schneider, S.G., Schneider, S., Silva, H.M., & Malvisi, F. (2006). Microstructural and mechanical characterization of biomedical Ti–Nb–Zr(–Ta) alloys. Materials Science and Engineering: A, 432(1-2), 108-112. doi: 10.1016/j.msea.2006.06.013.

    [5] Fakhr Nabavi, H., & Aliofkhazraei, M. (2019). Morphology, composition and electrochemical properties of bioactive-TiO2/HA on CP-Ti and Ti6Al4V substrates fabricated by alkali treatment of hybrid plasma electrolytic oxidation process (estimation of porosity from EIS results). Surface and Coatings Technology, 375, 266-291. doi: 10.1016/j.surfcoat.2019.07.032.

    [6] Fakhr Nabavi, H., Aliofkhazraei, A., & Sabour Rouhaghdam, A. (2017). Electrical characteristics and discharge properties of hybrid plasma electrolytic oxidation on titanium. Journal of Alloys and Compounds, 728, 464-475. doi: 10.1016/j.jallcom.2017.09.028.

    [7] Geetha, M., Singh, A.K., Asokamani, R., & Gogia, A.K. (2009). Ti based biomaterials, the ultimate choice for orthopaedic implants – a review. Progress in Materials Science, 54(3), 397-425. doi: 10.1016/j.pmatsci.2008.06.004.

    [8] Imbirovych, N.Y., Zvirko, O.I., & Kurzydlowski, K.-J. (2023). Morphology and porosity of the surface of titanium alloys after plasma-electrolytic oxidation in an alkaline environment with diatomite. Materials Science, 59(4), 451-458. doi: 10.1007/s11003-024-00797-4.

    [9] Jakubowicz, J. (2020). Special issue: Ti-based biomaterials: Synthesis, properties and applications. Materials, 13(7), article number 1696. doi: 10.3390/ma13071696.

    [10] Kaur, M., & Singh, K. (2019). Review on titanium and titanium based alloys as biomaterials for orthopaedic applications. Materials Science and Engineering: C, 102, 844-862. doi: 10.1016/j.msec.2019.04.064.

    [11] Korzhyk, V., Berdnikova, O., Stukhliak, P., Kushnarova, O., Zhao, J.J., & Skachkov, I. (2024). Strength and crack resistance structural criteria of composite coatings produced by the method of multi-chamber detonation spraying. Solid State Phenomena, 355, 123-129. doi: 10.4028/p-qjM7yA.

    [12] Kurup, A., Dhatrak, P., & Khasnis, N. (2021). Surface modification techniques of titanium and titanium alloys for biomedical dental applications: A review. Materials Today: Proceedings, 39, 84-90. doi: 10.1016/j.matpr.2020.06.163.

    [13] Chen, L., Wei, K., Qu, Y., Li, T., Chang, B., Liao, B., & Xue, W. (2018). Characterization of plasma electrolytic oxidation film on biomedical high niobium-containing β‑titanium alloy. Surface and Coatings Technology, 352, 295-301. doi: 10.1016/j.surfcoat.2018.08.025.

    [14] Lu, X., Blawert, C., Zheludkevich, M.L., & Kainer, K.U. (2015). Insights into plasma electrolytic oxidation treatment with particle addition. Corrosion Science, 101, 201-207. doi: 10.1016/j.ceramint.2024.08.484.

    [15] Mortazavi, G., Jiang, J., & Meletis, E.I. (2019). Investigation of the plasma electrolytic oxidation mechanism of titanium. Applied Surface Science, 488, 370-382. doi: 10.1016/j.apsusc.2019.05.250.

    [16] Qin, J., Shi, X., Li, H., Zhao, R., Li, G., Zhang, S., Ding, L., Cui, X., Zhao, Y., & Zhang, R. (2022). Performance and failure process of green recycling solutions for preparing high degradation resistance coating on biomedical magnesium alloys. Green Chemistry, 24, 8113-8130. doi: 10.1039/D2GC02638D.

    [17] Riabchykov, M., Furs, T., Alexandrov, A., Tsykhanovska, I., Hulai, O., & Shemet, V. (2023a). Specified parameters in designing porous materials using magnetic nanotechnologies. Journal of Engineering Sciences, 10(2), 56-62. doi: 10.21272/jes.2023.10(2).c7.

    [18] Riabchykov, M., Tkachuk, O., Nazarchuk, L., & Alexandrov, A. (2023b). Conditions for the open pores formation in medical textile materials for the treatment of wounds using iron oxide nanopowders. Materials Research Express, 10(1), article number 015401. doi: 10.1088/2053-1591/acadcf.

    [19] Usmaniya, N., Shishir, R., Ponnilavan, V., Rama Krishna, L., & Rameshbabu, N. (2024). Development of hydroxyapatite/bioactive glass incorporated chitosan layer on plasma electrolytic oxidised ZM21 alloy for temporary implant applications. Journal of Alloys and Compounds, 1004, article number 175723. doi: 10.1016/j.jallcom.2024.175723.

    [20] Yuferov, Yu., & Borodianskiy, K. (2024). Ca/P in situ introduction for enhancing coating biocompatibility via plasma electrolytic oxidation in low-temperature molten salt. Open Ceramics, 18, article number 100602. doi: 10.1016/j.oceram.2024.100602.